Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) CAS:32993-05-8

Chlorocyclopentadienylbis (triphenylphosphine)ruthenium (II) ke sesebelisoa se sebetsang ka bongata se nang le mefuta e mengata ea ts'ebeliso ho tsoakaneng ha lintho tse phelang. E 'ngoe ea ts'ebeliso ea eona ea mantlha ke ho kenngoa ha metsoako e sa koaheloang, joalo ka li-alkenes, li-alkynes, le metsoako e nkhang hamonate e sebetsang. Motsoako ona o bontša ts'ebetso e phahameng ea ho kenya le ho khetha liphetohong tsena, e leng se etsang hore e be sesebelisoa sa bohlokoa bakeng sa tlhahiso ea lik'hemik'hale tse ntle, metsoako ea meriana le lik'hemik'hale tsa temo. Ntle le hydrogenation, motsoako ona o boetse o sebelisoa liketsong tsa isomerization, moo o ka nolofatsang ho hlophisoa bocha ha litlamo tse peli le lihlopha tse ling tse sebetsang limolek'huleng tsa lintho tse phelang. Bokhoni ba oona ba ho kenya tšebetsong lits'ebetso tsa isomerization ka katleho e phahameng le taolo bo etsa hore e be molemo ho tsoakaneng ha limolek'hule tse rarahaneng tsa lintho tse phelang le lihlahisoa tsa tlhaho. Ho feta moo, Chlorocyclopentadienylbis (triphenylphosphine)ruthenium (II) e fumana lits'ebetso lefapheng la liketso tsa ho theha maqhama tsa CC le CX. E sebelisitsoe ho tsoakaneng ha metsoako e fapaneng ea lintho tse phelang, ho kenyeletsoa lihlahisoa tse rarahaneng tsa tlhaho, meriana le lisebelisoa tse sebetsang. Mosebetsi oa eona oa ho susumetsa ka tlas'a maemo a bonolo le ho lumellana ha eona le lihlopha tse ngata tse sebetsang ho e etsa hore e be mohloli oa bohlokoa bakeng sa kaho ea litlamo tse ncha tsa carbon-carbon le carbon-heteroatom. Ho feta moo, motsoako ona oa ruthenium o bontšitse tšepiso nts'etsopele ea mahlale a matla a tsitsitseng. E sebelisoa phetohong ea ho susumetsa ka ho susumetsa ea metsoako e nkiloeng ho biomass le ho kopanngoa ha mafura le lik'hemik'hale tse nchafatsoang. Bokhoni ba eona ba ho thusa ho fetola ka katleho le ka khetho ea li-feedstock tse nchafatsoang bo tlatsetsa ho ntšetsong pele ea lits'ebetso tsa lik'hemik'hale tse tsitsitseng le tse mosa tikolohong. Ka bokhutšoanyane, Chlorocyclopentadienylbis (triphenylphosphine)ruthenium (II) ke mohloli o feto-fetohang o nang le lits'ebetso tsa hydrogenation, isomerization, liketso tsa ho theha maqhama, le mahlale a matla a tsitsitseng. Botsitso ba eona, reactivity, le khetho li etsa hore e be sesebelisoa sa bohlokoa ho kopanyeng lintho tse phelang le nts'etsopele ea lits'ebetso tsa lik'hemik'hale tse tsitsitseng.