Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II)) CAS:1026995-71-0

Motsoako ona o sebediswa haholo e le ntho e thusang diphetohong tse fapaneng tsa dikhemikhale, ho kenyeletswa ho thehwa ha maqhama a khabone le khabone, hydrogenation, le dikarabelo tse kopanyang. Sebopeho sa wona se ikgethang se o dumella ho kenya tshebetsong le ho sebetsa di-substrate tse fapaneng tsa tlhaho, e leng se lebisang ho thehweng ha dimolek'hule tse rarahaneng tse nang le kgetho e phahameng le bokgoni. Ho feta moo, (Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II) e bontšitse liphetho tse tšepisang ho catalysis e sa lekanang, moo e ka hlahisang chirality ka har'a limolek'hule tse arabelang, e leng se nolofalletsang tlhahiso ea metsoako ea enantiopure. Thepa ena e bohlokoa haholo indastering ea meriana, moo limolek'hule tsa enantiopure li leng bohlokoa bakeng sa nts'etsopele ea lithethefatsi. Ho tenyetseha ha motsoako le reactivity ea oona ho etsa hore e be sesebelisoa sa bohlokoa k'hemistring ea maiketsetso. E ka nolofatsa liphetoho tse phephetsang, joalo ka ho thehoa ha litlamo tsa carbon-heteroatom le ho kengoa tšebetsong ha li-substrate tse sa sebetseng, ho atolosa menyetla ea maiketsetso bakeng sa bafuputsi. Qetellong, (Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II) ke motsoako o rarahaneng o nang le lits'ebetso tsa bohlokoa e le catalyst tlhahisong ea lintho tse phelang. Bokhoni ba eona ba ho kenya tšebetsong li-substrate tse fapaneng le ho kenya tšebetsong chirality bo e etsa sesebelisoa sa bohlokoa tlhahisong ea limolek'hule tse rarahaneng, ho kenyeletsoa le metsoako ea enantiopure bakeng sa merero ea meriana.