carbanide, chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

Palladium(II) Chloro complex [(C8H12)(Cl)Pd] e thehwa ka ho hokahana pakeng tsa PdCl4 le dimolek'hule tsa trans-(1R,5S)-cycloocta-1,5-diene ka dibonto tsa dative. Sehlahiswa se hlahang se na le dienyl ligand e le nngwe e tlamilweng setsing se seng le se seng sa tse nne tsa tshepe ka ho hokahana ha eta. Complex ena e na le botsitso bo phahameng ba mocheso ka lebaka la matla a matla a dimolek'hule ka hara sebopeho. Tshebediso ya yona e itshetlehile haholo ditsamaisong tsa catalytic tse kenyeletsang karabelo ya ho kopanya e tshekaletseng. Mohlala, mofuta ona o thusa ho thehwa ha bonto ya C-C nakong ya Suzuki Coupling Reaction e kenyeletsang ho kopanya diathomo tsa khabone tse kopantsweng tsa sp2 hammoho ho sebediswa di-boronic acid e le di-nucleophiles. Bonto e ntjha e hlahang e ntlafatsa thepa ya thepa e sebediswang disebedisweng tsa elektroniki kahoo e etsa hore di sebetse hantle. Ho feta moo, catalyst ena e fumana tshebediso karabelong ya ho kopanya ya Sonogashira moo diathomo tse kopantsweng tsa sp di kopantsweng hammoho ho sebediswa di-alkynes tse lebisang ho thehweng ha bonto ya C-C ka hona ho thehwa dihlopha tse ntjha tse sebetsang tse nang le ditshebediso tse ka bang teng mafapheng a fapaneng ho kenyeletswa le ho kopanya dithethefatsi le saense ya thepa.