bromotris (triphenylphosphine) rhodium (I) CAS: 14973-89-8

Sesebediswa sa Wilkinson se sebediswa diphetohong tse fapaneng tsa dikhemikhale, ho kenyeletswa le hydrogenation, hydrosilylation, le hydroformylation. Se boetse se sebediswa tlhahisong ya dikhemikhale tse ntle, meriana le thepa e tswetseng pele. Bokgoni ba sesebediswa sa ho thusa ditsamaiso tse kgethilweng le tse sebetsang tsa ho etsa dikhemikhale bo se entse sesebediswa sa bohlokwa ntshetsopeleng ya mekgwa e metjha ya maiketsetso le tlhahisong ya dihlahiswa tsa dikhemikhale tsa bohlokwa.

E 'ngoe ea lits'ebeliso tsa bohlokoa ka ho fetisisa tsa catalyst ea Wilkinson ke tlhahisong ea li-aldehyde tse otlolohileng ka karabelo ea hydroformylation. Catalyst e khothalletsa ho eketsoa ha carbon monoxide le hydrogen ka khetho ho olefin, e leng se fellang ka ho thehoa ha aldehyde. Karabelo ena e sebelisoa haholo tlhahisong ea li-plasticizer, sesepa sa ho hlatsoa le lik'hemik'hale tse ling tsa bohlokoa tsa indasteri.

Sesebediswa sa Wilkinson se boetse se sebediswa ho kopanyeng dihlahiswa tse rarahaneng tsa tlhaho le dihlahiswa tse sebetsanang le meriana. Dibopeho tsa sona tse ikgethang le tshebetso ya sona di etsa hore e be sesebediswa sa bohlokwa ho ntshetseng pele diphetoho tse fapaneng tsa dikhemikhale. Ho feta moo, se sebediswa tlhahisong ya dikhemikhale tse ikgethang, tse kang di-chiral ligand, le thepa e tswetseng pele, tse kang di-polymer tse tsamaisang motlakase.

Ka kakaretso, Bromotris (triphenylphosphine) rhodium (I) kapa catalyst ea Wilkinson ke motsoako o feto-fetohang o nang le lits'ebetso tse kholo tlhahisong ea lintho tse phelang, saense ea thepa, le lits'ebetso tsa lik'hemik'hale tsa indasteri. Tšebeliso ea eona e ka bang teng e atolohela nts'etsopele ea libeteri tse sebetsang hantle le lisele tsa mafura, moo botsitso le ts'ebetso mochesong o phahameng li leng bohlokoa. Bohlokoa ba motsoako tšimong ea k'hemistri ea lintho tse phelang le tlhahiso ea lik'hemik'hale tsa indasteri bo ke ke ba feteletsoa.